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An {Fe60} tetrahedral cage: building nanoscopic molecular assemblies through cyanometallate and alkoxo linkers

Abstract : A nanoscopic {Fe60} coordination cage (approximately 3 nm) was prepared by the self assembly of a partially blocked tricyanidoferrate(III) complex and tris(alkoxo)-based iron(III) coordination motifs. This cage is a rare example of a mixed cyanido/alkoxo-bridged high nuclearity complex and it exemplifies the great potential of this new synthetic route to generate uncommon molecular architectures using cyanometallates as metalloligands versus alkoxo-based polynuclear entities.
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Submitted on : Thursday, August 4, 2022 - 12:07:00 PM
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J.-R. Jiménez, A. Mondal, L.-M. Chamoreau, P. Fertey, F. Tuna, et al.. An {Fe60} tetrahedral cage: building nanoscopic molecular assemblies through cyanometallate and alkoxo linkers. Dalton Transactions, Royal Society of Chemistry, 2016, 45 (44), pp.17610--17615. ⟨10.1039/C6DT03151J⟩. ⟨hal-01727616⟩

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