Pd-H from Pd/C and Triethylamine: Implications in Palladium Catalysed Reactions Involving Amines

Yoann Coquerel (1) , Paul Brémond (1) , Jean Rodriguez (1)

1 STeRéO

The palladium hydride-iminium complex generated from Pd/C and triethylamine catalyses the isomerisation of allylic alcohols into carbonyl compounds, and Pd/C catalyses the conjugate reduction of activated double bonds using triethylamine as the source of the two newly incorporated hydrogen atoms via the same complex.

Mots clés: Catalysis; Palladium hydride; Triethylamine; Isomerisation; Conjugate reduction

Domaines: Chimie organique

Yoann Coquerel, Paul Brémond, Jean Rodriguez. Pd-H from Pd/C and Triethylamine: Implications in Palladium Catalysed Reactions Involving Amines. Journal of Organometallic Chemistry, 2007, 692 (22), pp.4805-4808. ⟨10.1016/j.jorganchem.2007.05.053⟩. ⟨hal-00676968⟩