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Organocatalytic Synthesis of 1,2,3-Triazoles from Unactivated Ketones and Arylazides

Mokhtaria Belkheira 1, 2 Douniazad El Abed 1 Jean-Marc Pons 3, * Cyril Bressy 3, * 
* Corresponding author
3 STeRéO
ISM2 - Institut des Sciences Moléculaires de Marseille
Abstract : Organo-click reaction: A new and complementary method to Huisgen's metal-catalyzed triazole synthesis is described using unactivated ketones and arylazides as the substrates and proline as an organocatalyst. Dramatic acceleration was observed for this reaction using microwave activation and high regio- and chemoselectivities were obtained for a wide range of ketones and arylazides
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Submitted on : Wednesday, March 14, 2012 - 11:23:36 AM
Last modification on : Tuesday, December 14, 2021 - 8:36:12 AM

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Mokhtaria Belkheira, Douniazad El Abed, Jean-Marc Pons, Cyril Bressy. Organocatalytic Synthesis of 1,2,3-Triazoles from Unactivated Ketones and Arylazides. Chemistry - A European Journal, Wiley-VCH Verlag, 2011, 17, pp.12917 - 12921. ⟨10.1002/chem.201102046⟩. ⟨hal-00678912⟩

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