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TDAE Strategy in the Benzoxazolone Series: Synthesis and Reactivity of a New Benzoxazolinonic Anion

Aïda R. Nadji-Boukrouche 1, 2, 3 Omar Khoumeri 1 Thierry Terme 1 Messaoud Liacha 3 Patrice Vanelle 1
1 ICR - Institut de Chimie Radicalaire
2 Département de Génie des Procédés
3 Laboratoire de Synthèse et de Biocatalyse Organique (LSBO)
Abstract : We describe an original pathway to produce new 5-substituted 3-methyl-6-nitro-benzoxazolones by the reaction of aromatic carbonyl and α-carbonyl ester derivatives with a benzoxazolinonic anion formed exclusively via the TDAE strategy.
Keywords : METHODOLOGY RING ALDEHYDES LIGANDS 2(3H)-BENZOXAZOLONE benzylic alcohols oxiranes ORIGINAL SYNTHESIS DERIVATIVES benzoxazolinonic anion benzoxazolone TDAE
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Aïda R. Nadji-Boukrouche, Omar Khoumeri, Thierry Terme, Messaoud Liacha, Patrice Vanelle. TDAE Strategy in the Benzoxazolone Series: Synthesis and Reactivity of a New Benzoxazolinonic Anion. Molecules, MDPI, 2015, 20, pp.1262-1276. ⟨10.3390/molecules20011262⟩. ⟨hal-01234886⟩

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