Bis-phosphine allene ligand: coordination chemistry and preliminary applications in catalysis

Avassaya Vanitcha (1) , Cecilia Damelincourt (1) , Geoffrey Gontard (1) , Nicolas Vanthuyne (2) , Virginie Mouriès-Mansuy (1) , Louis Fensterbank (1)

1 IPCM - Institut Parisien de Chimie Moléculaire
2 ISM2 - Institut des Sciences Moléculaires de Marseille

A 1,3-bis-diphenylphosphine allene can give rise to new coordination complexes with palladium, platinum and gold metals. These complexes were fully characterized by NMR, HRMS and X-ray diffraction analysis. For gold(I), the corresponding dinuclear complex has been used in a series of diagnostic catalytic reactions and gave promising preliminary results in asymmetric catalysis.

Domaines: Chimie

Avassaya Vanitcha, Cecilia Damelincourt, Geoffrey Gontard, Nicolas Vanthuyne, Virginie Mouriès-Mansuy, et al.. Bis-phosphine allene ligand: coordination chemistry and preliminary applications in catalysis. Chemical Communications, 2016, 52, pp.6785-6788 ⟨10.1039/c6cc02316a⟩. ⟨hal-01311658⟩