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Article Dans Une Revue Advanced Synthesis and Catalysis Année : 2015

Synthesis of Allenes Bearing Phosphine Oxide Groups and Investigation of Their Reactivity toward Gold Complexes

Résumé

A collection of phosphine oxide allenes has been prepared. Their coordination to gold(I) has been studied giving new coordination complexes when a pendant pyridine moiety was present. Alternatively, their gold(I)-catalyzed cycloisomerization has proven to be quite efficient. An almost complete axial-to-central chirality transfer in the cyclization process was observed, opening the potential access to valuable enantiopure phosphorus derivatives.

Domaines

Chimie organique

Dates et versions

hal-01397961 , version 1 (16-11-2016)

Identifiants

Citer

Avassaya Vanitcha, Geoffrey Gontard, Nicolas Vanthuyne, Etienne Derat, Virginie Mouriès-Mansuy, et al.. Synthesis of Allenes Bearing Phosphine Oxide Groups and Investigation of Their Reactivity toward Gold Complexes. Advanced Synthesis and Catalysis, 2015, 357 (10, SI), pp.2213-2218. ⟨10.1002/adsc.201500345⟩. ⟨hal-01397961⟩
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