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Article Dans Une Revue Organometallics Année : 2014

Secondary Phosphine Oxide-Gold(I) Complexes and Their First Application in Catalysis

Résumé

A series of new secondary phosphine oxide (SPO)-gold(1) complexes have been synthesized and characterized by X-ray crystallography. Complexes exhibited dimeric structures interconnected by O-H center dot center dot center dot Cl hydrogen bonds. Their first use in homogeneous catalysis is reported and suggests a broad field of application in prototypical enyne cycloisomerization and hydroxy- and methoxycyclization reactions.

Domaines

Chimie organique
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Dates et versions

hal-01397972 , version 1 (16-11-2016)

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Felix Schroeder, Coralie Tugny, Elise Salanouve, Hervé Clavier, Laurent Giordano, et al.. Secondary Phosphine Oxide-Gold(I) Complexes and Their First Application in Catalysis. Organometallics, 2014, 33 (15), pp.4051-4056. ⟨10.1021/om500568q⟩. ⟨hal-01397972⟩

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