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Regio- and Diastereoselective Platinum-Catalyzed Tandem [2+1]/[3+2] Cycloaddition Sequence

Abstract : Platinum complexes bearing phosphinous acids have efficiently promoted a tandem intermolecular sequence of [2+1]/[3+2] cycloaddition reactions. This process gave access to novel tricyclic systems and the cascade reactions were regio- and diastereoselective (see scheme; Cy=cyclohexyl). The [3+2] cycloaddition reaction was investigated further and two different alkyne partners were used.
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https://hal.archives-ouvertes.fr/hal-01409129
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Submitted on : Monday, December 5, 2016 - 4:45:08 PM
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Thierry Achard, Aymeric Lepronier, Yves Gimbert, Hervé Clavier, Laurent Giordano, et al.. Regio- and Diastereoselective Platinum-Catalyzed Tandem [2+1]/[3+2] Cycloaddition Sequence. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2011, ⟨10.1002/anie.201007992⟩. ⟨hal-01409129⟩

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