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Mild and Metal-Free Regioselective 1,2-Addition of Carbon Nucleophiles to α,β-Unsaturated Imines

Abstract : A mild and metal-free regioselective 1,2-addition of carbon nucleophiles to α,β-unsaturated imines has been developed. Good yields and total regioselectivities were achieved by addition of p-nitro-benzyl chloride or 2,3-bis(bromomethyl)quinoxaline to α,β-unsaturated tosylimines.
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https://hal-amu.archives-ouvertes.fr/hal-01425635
Contributor : Cédric Spitz <>
Submitted on : Tuesday, January 3, 2017 - 4:55:28 PM
Last modification on : Thursday, January 18, 2018 - 2:00:21 AM
Long-term archiving on: : Tuesday, April 4, 2017 - 2:38:55 PM

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Cédric Spitz, Thierry Terme, Patrice Vanelle. Mild and Metal-Free Regioselective 1,2-Addition of Carbon Nucleophiles to α,β-Unsaturated Imines. SYNLETT, Georg Thieme Verlag, 2016, 27, pp.301 - 303. ⟨10.1055/s-0035-1560574⟩. ⟨hal-01425635⟩

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