Mild and Metal-Free Regioselective 1,2-Addition of Carbon Nucleophiles to α,β-Unsaturated Imines - Archive ouverte HAL Access content directly
Journal Articles SYNLETT Year : 2016

Mild and Metal-Free Regioselective 1,2-Addition of Carbon Nucleophiles to α,β-Unsaturated Imines

Abstract

A mild and metal-free regioselective 1,2-addition of carbon nucleophiles to α,β-unsaturated imines has been developed. Good yields and total regioselectivities were achieved by addition of p-nitro-benzyl chloride or 2,3-bis(bromomethyl)quinoxaline to α,β-unsaturated tosylimines.
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Dates and versions

hal-01425635 , version 1 (03-01-2017)

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Cédric Spitz, Thierry Terme, Patrice Vanelle. Mild and Metal-Free Regioselective 1,2-Addition of Carbon Nucleophiles to α,β-Unsaturated Imines. SYNLETT, 2016, 27, pp.301 - 303. ⟨10.1055/s-0035-1560574⟩. ⟨hal-01425635⟩
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