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3.10 - Nitroxide-Mediated Polymerization

J. Nicolas Y. Guillaneuf Denis Bertin 1 D. Gigmes 1 B. Charleux 2
1 ICR - Institut de Chimie Radicalaire
2 LCP - Chimie des polymères
UPMC - Université Pierre et Marie Curie - Paris 6, IPCM - Institut Parisien de Chimie Moléculaire, CNRS - Centre National de la Recherche Scientifique : UMR7610
Abstract : This chapter covers the main achievements in nitroxide-mediated polymerization (NMP) from its discovery to late 2010. The various synthetic approaches to nitroxides and alkoxyamines are first presented. The range of monomers for NMP, kinetic features, as well as polymerization in aqueous dispersed media are also discussed. Finally, functionalization strategies of NMP-derived polymers, macromolecular architectures, and biomaterials are detailed.
Keywords : Self-assembly Controlled radical polymerization Kinetics Macromolecular architecture Nitroxide Nitroxide-mediated polymerization Polymerization process Block copolymer Bioconjugates Aqueous dispersed media Alkoxyamine
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https://hal-amu.archives-ouvertes.fr/hal-01460403
Contributor : Didier Gigmes <>
Submitted on : Tuesday, February 7, 2017 - 4:39:13 PM
Last modification on : Monday, May 11, 2020 - 7:50:35 PM

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J. Nicolas, Y. Guillaneuf, Denis Bertin, D. Gigmes, B. Charleux. 3.10 - Nitroxide-Mediated Polymerization. Möller, Krzysztof MatyjaszewskiMartin. Polymer Science: A Comprehensive Reference, Elsevier, pp.277--350, 2012, 978-0-08-087862-1. ⟨hal-01460403⟩

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