Rationalizing the F...S interaction discovered within a tetrafluorophenylazido-containing bola-phospholipid

Yi Xia (1) , Stéphane Viel (2) , Yang Wang (1) , Fabio Ziarelli (3) , Erik Laurini (4) , Paola Posocco (4) , Maurizio Fermeglia (4) , Fanqi Qu (5) , Sabrina Pricl (4) , Ling Peng (1)

1 CINaM - Centre Interdisciplinaire de Nanoscience de Marseille
2 ICR - Institut de Chimie Radicalaire
3 AMU SPEC - Spectropôle - Aix Marseille Université
4 Università degli studi di Trieste = University of Trieste
5 Wuhan University [China]

A bola-lipid bearing tetrafluorophenylazido chromophore in the diacyl chain displayed puzzling F-19 NMR, leading to the evidence and rationalization of a F center dot center dot center dot S weak interaction that is important for altering molecular structures and imposing novel and special properties on fluorinated compounds.

Domains: Chemical Sciences

Yi Xia, Stéphane Viel, Yang Wang, Fabio Ziarelli, Erik Laurini, et al.. Rationalizing the F...S interaction discovered within a tetrafluorophenylazido-containing bola-phospholipid. Chemical Communications, 2012, 48 (36), pp.4284--4286. ⟨10.1039/c2cc18147a⟩. ⟨hal-01460422⟩