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Organic multishell isostructural host-guest crystals: fullerenes C-60 inside a nitroxide open framework

Abstract : The dinitroxide biradical bTbk crystallizes forming hexagonal open frameworks with one-dimensional corrugated channels filled with crystallization solvent. The large pockets constitutive of the channels allowed the inclusion of C-60 in the paramagnetic network. The rapidity and high fidelity of crystal growth were used to prepare isostructural multilayer host-guest crystals successively stained with C-60.
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https://hal-amu.archives-ouvertes.fr/hal-01460437
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Submitted on : Tuesday, February 7, 2017 - 4:41:44 PM
Last modification on : Tuesday, January 30, 2018 - 12:28:02 PM

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David Bardelang, Michel Giorgi, Cedric Pardanaud, Virginie Hornebecq, Egon Rizzato, et al.. Organic multishell isostructural host-guest crystals: fullerenes C-60 inside a nitroxide open framework. Chemical Communications, Royal Society of Chemistry, 2013, 49 (34), pp.3519--3521. ⟨10.1039/c3cc00170a⟩. ⟨hal-01460437⟩

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