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Enantioselective Syntheses of Furan Atropisomers by an Oxidative Central-to-Axial Chirality Conversion Strategy

Abstract : For the first time, enantiomerically enriched atropoisomeric furans have been accessed using a central- to-axial chirality conversion strategy. Hence, oxidation of the enantioenriched dihydrofuran precursors gave rise to axially chiral furans with high enantiopurities accounting from excellent conversion percentages (cp) in most cases.
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Submitted on : Tuesday, June 6, 2017 - 5:59:08 PM
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Long-term archiving on: : Thursday, September 7, 2017 - 2:19:42 PM

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Vivek S Raut, Marion Jean, Nicolas Vanthuyne, Christian Roussel, Thierry Constantieux, et al.. Enantioselective Syntheses of Furan Atropisomers by an Oxidative Central-to-Axial Chirality Conversion Strategy. Journal of the American Chemical Society, American Chemical Society, 2017, 139 (6), pp.2140-2143. ⟨10.1021/jacs.6b11079⟩. ⟨hal-01533761⟩

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