A. Panossian, F. R. Leroux, F. Colobert, S. Shirakawa, S. Liu et al., (e) Special issue (f) For a highlight, see: Quinonero, O.; Bressy, Chem. Soc. Rev. Chem. -Asian J. Tetrahedron C.; Bugaut, X. Angew. Chem., Int. Ed, vol.44, issue.536, pp.3418-5157, 2014.

R. De, C. K. Pesciaioli, F. Li, G. Ess, and D. H. , 7) For recent examples of enantioselective synthesis of chiral biaryls, see: (a, List, B. Angew. Chem., Int. Ed, vol.115, issue.52, pp.11239-9293, 2013.

C. Sperandio, E. Moretti, A. Di-sabato, R. Salvio, M. Bella et al., (a) For a review on atropisomerism in heteroaromatic compounds Perkin Trans During the revision process of this paper, the group of Shi and Li published an article describing the enantioselective construction of axially chiral naphthyl-indole skeletons (11) In its strict definition, conversion of chirality is a chemical process consisting in the destruction of a stereogenic element on a molecule with the simultaneous installation of another stereogenic element of a different nature. For further details (12) (a) For seminal studies, see: Berson For other examples of central-to-axial chirality conversion to access all-carbon biaryls, see, 2012, 105, 1?188. (b) Dynamic Stereochemistry of Chiral Compounds: Principles and Applications; RSC: Cambridge, pp.6525-7261, 1955.

W. Raimondi, D. Dauzonne, T. Constantieux, D. Bonne, J. Rodriguez et al., (e) For the synthesis of achiral furans from (Z)-(2-halo-2-nitroethenyl)benzenes, see, J. Eur. J. Org. Chem. C, vol.49, issue.15, p.6119, 2012.

U. Kaya, D. Hack, D. Enders, S. Lu, P. Zheng et al., (19) (2S,3S)-3d, (aS)-4d, (1R,2S)-9m and (aS)-10m refer to CCDC 1505555, CCDC 1505557, CCDC 1505556, CCDC 1505558 respectively, which contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk. (20) With other hindered aryl groups (e.g., 2-methylnaphthyl, 2- bromo-6-methylphenyl, 2-methyl-6-nitrophenyl, the corresponding furans proved unstable during the oxidation step. (21) With fluorine atom, the barrier to rotation was only of 85 kJ mol ?1 preventing the isolation of a stable atropisomer of the corresponding furan, pp.253-271, 2012.