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Chiral Fidelity in the Diastereoselective and Enantiospecific Synthesis of Indenes from Axially Chiral Benzylidene Cyclanes

Abstract : Enantioenriched indenes were reached through a chirality conversion strategy using original axially chiral benzylidene cyclanes. Good to high remote diastereocon-trol and excellent enantiocontrol were observed in this cascade involving copper-catalyzed homologation of terminal alkynes, in situ allenoate formation and Alder-ene cyclization.
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Submitted on : Saturday, April 14, 2018 - 5:52:26 PM
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Dominique Mouysset, Cyril Tessonnier, Aura Tintaru, Frederic Dumur, Marion Jean, et al.. Chiral Fidelity in the Diastereoselective and Enantiospecific Synthesis of Indenes from Axially Chiral Benzylidene Cyclanes. Chemistry - A European Journal, Wiley-VCH Verlag, 2017, 23 (35), pp.8375 - 8379. ⟨10.1002/chem.201701501⟩. ⟨hal-01682754⟩

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