C. Borie, L. Ackermann, M. Nechab, B. Gabriele, R. Mancuso et al., Enantioselective syntheses of indanes: from organocatalysis to C???H functionalization, Chemical Society Reviews, vol.54, issue.5, pp.1368-1386, 2016.
DOI : 10.1002/anie.201409659

URL : https://hal.archives-ouvertes.fr/hal-01406321

T. Hashimoto, Y. Kawamata, and K. Maruoka, For recent applications as an organocatalyst see, Nat. Chem. 2014, vol.6, pp.702-705

M. Egi, K. Shimizu, M. Kamiya, Y. Ota, and S. Akai, Central???axial???central chirality transfer: asymmetric synthesis of highly substituted indenes bearing a stereogenic quaternary carbon center from optically active propargyl alcohols, Chemical Communications, vol.5, issue.2, pp.380-383, 2015.
DOI : 10.1021/ol030061c

J. Clayden, A. Lund, L. Vallverdffl, and M. Helliwell, Ultra-remote stereocontrol by conformational communication of information along a carbon chain, Nature, vol.90, issue.7011, pp.966-971, 2004.
DOI : 10.1016/S0040-4020(01)96496-8

W. H. Perkin, J. , W. L. Pope-b-)-w, J. Perkin, W. L. Pope et al., CIX.???Experiments on the synthesis of 1-methylcyclo-hexylidene-4-acetic acid, [graphic omitted]. Part I, J. Chem. Soc., Trans., vol.93, issue.0, pp.1075-1085, 1908.
DOI : 10.1039/CT9089301075

I. Sato, R. Sugie, Y. Matsueda, Y. Furumura, and K. Soai, Asymmetric Synthesis Utilizing Circularly Polarized Light Mediated by the Photoequilibrium of Chiral Olefins in Conjunction with Asymmetric Autocatalysis, Angewandte Chemie International Edition, vol.43, issue.34, pp.4490-4492, 2004.
DOI : 10.1002/anie.200454162

. Angew, M. Chem, N. Nechab, . Vanthuyne, and . Org, For previous use in cascade reactions in our group see: b), Adv. Synth. Catal, vol.116, issue.354, pp.3664-3666, 1987.

T. Rein and T. M. Pedersen, For review on the enantioselective synthesis of alkylidene cycloalkanes see: a), pp.579-594, 2002.

M. Walborsky, K. Gawronska, and J. K. Gawronski, Synthesis and chiroptical properties of .gamma.-substituted rigid and conformationally flexible systems having 1,3-diene and .alpha.,.beta.-unsaturated carbonyl chromophores. The planar diene rule, Journal of the American Chemical Society, vol.109, issue.22, pp.6719-6726, 1987.
DOI : 10.1021/ja00256a027

K. Närhi, J. Franzøn, and J. Bäckvall, An Unexpectedly Mild Thermal Alder???Ene-Type Cyclization of Enallenes, The Journal of Organic Chemistry, vol.71, issue.7, pp.2914-2917, 2006.
DOI : 10.1021/jo060013g

M. Suarez and G. B. Schuster, Photoresolution of an Axially Chiral Bicyclo[3.3.0]octan-3-one: Phototriggers for a Liquid-Crystal-Based Optical Switch, Journal of the American Chemical Society, vol.117, issue.25, pp.6732-6738, 1995.
DOI : 10.1021/ja00130a013

R. Sanz, A. Martínez, P. García-garcía, M. A. Fernµndez-rodríguez, M. A. Rashid et al., Halocyclization of o-(alkynyl)styrenes. Synthesis of 3-halo-1H-indenes, Chemical Communications, vol.46, issue.39, pp.7427-7429, 2010.
DOI : 10.1039/c0cc02590a

K. Fukui, The path of chemical reactions - the IRC approach, Accounts of Chemical Research, vol.14, issue.12, pp.363-368, 1981.
DOI : 10.1021/ar00072a001

D. Campolo, T. Arif, C. Borie, D. Mouysset, N. Vanthuyne et al., Double Transfer of Chirality in Organocopper-Mediated bis(Alkylating) Cycloisomerization of Enediynes, Angewandte Chemie International Edition, vol.14, issue.12, pp.3227-3231, 2014.
DOI : 10.1021/ol300227a

URL : https://hal.archives-ouvertes.fr/hal-01406326