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Sequence-coded ATRP macroinitiators

Abstract : Sequence-coded oligourethanes were tested as macroinitiators for the atom transfer radical polymerization (ATRP) of styrene. These oligomers were synthesized by solid-phase orthogonal iterative chemistry and transformed into ATRP initiators using a three-step modification procedure. A controlled radical polymerization behavior was observed with these macroinitiators, thus opening interesting opportunies for the synthesis of macromolecular architectures containing sequence-defined segments.
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https://hal-amu.archives-ouvertes.fr/hal-01774178
Contributor : Marlene Delhaye <>
Submitted on : Monday, April 23, 2018 - 2:41:20 PM
Last modification on : Thursday, May 7, 2020 - 1:37:23 AM

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Sofia Telitel, Benoit Eric Petit, Salome Poyer, Laurence Charles, Jean-Francois Lutz. Sequence-coded ATRP macroinitiators. Polymer Chemistry, Royal Society of Chemistry - RSC, 2017, 8 (34), pp.4988-4991. ⟨10.1039/c7py00496f⟩. ⟨hal-01774178⟩

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