Abstract : Sequence-coded oligourethanes were tested as macroinitiators for the atom transfer radical polymerization (ATRP) of styrene. These oligomers were synthesized by solid-phase orthogonal iterative chemistry and transformed into ATRP initiators using a three-step modification procedure. A controlled radical polymerization behavior was observed with these macroinitiators, thus opening interesting opportunies for the synthesis of macromolecular architectures containing sequence-defined segments.
https://hal-amu.archives-ouvertes.fr/hal-01774178 Contributor : Marlene DelhayeConnect in order to contact the contributor Submitted on : Monday, April 23, 2018 - 2:41:20 PM Last modification on : Wednesday, November 3, 2021 - 9:42:54 AM