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Journal Articles Polymer Chemistry Year : 2017

Sequence-coded ATRP macroinitiators

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Abstract

Sequence-coded oligourethanes were tested as macroinitiators for the atom transfer radical polymerization (ATRP) of styrene. These oligomers were synthesized by solid-phase orthogonal iterative chemistry and transformed into ATRP initiators using a three-step modification procedure. A controlled radical polymerization behavior was observed with these macroinitiators, thus opening interesting opportunies for the synthesis of macromolecular architectures containing sequence-defined segments.
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Dates and versions

hal-01774178 , version 1 (23-04-2018)

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Sofia Telitel, Benoit Eric Petit, Salome Poyer, Laurence Charles, Jean-Francois Lutz. Sequence-coded ATRP macroinitiators. Polymer Chemistry, 2017, 8 (34), pp.4988-4991. ⟨10.1039/c7py00496f⟩. ⟨hal-01774178⟩
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