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Mechanosynthesized copper(I) complex based initiating systems for redox polymerization: towards upgraded oxidizing and reducing agents

P. Garra F. Dumur 1 A. Al Mousawi 2, 3 B. Graff 4 D. Gigmes 1 F. Morlet-Savary 2 C. Dietlin J. P. Fouassier J. Lalevee 2
1 ICR - Institut de Chimie Radicalaire
2 IS2M - Institut de Science des Matériaux de Mulhouse
3 LU - Lebanese University [Beirut]
4 CNR - Compagnie Nationale du Rhône
Abstract : Significant improvements of the recently proposed Cu(I)/vitamin C + water/dibenzoyl peroxide (BPO) system for the redox free radical polymerization of methacrylates in air are presented here, the goal being to avoid the presence of water and to eliminate the unstable BPO compound. Additionally, the use of mechanosynthesized Cu(I) complexes bearing cheap triphenylphosphine and methylpyridine ligands, allowed us to reduce the economical and synthesis costs significantly. Water-free reducing agents such as 6-O-palmitoyl-L-ascorbic acid, organotin or hydrazine derivatives are evaluated. Cumene hydroperoxide and tert-butyl perbenzoate are proposed as a replacement for less stable BPO. Most of these novel combinations are more efficient in air than the usual amine/benzoylperoxide system (4-N, N-TMA/BPO) reference especially at the sample surface. Among them, Cu(I)/organotin/cumene hydroperoxide appears as an efficient and competitive alternative to the conventional amine/BPO couple.
Keywords : confocal raman microscopy cure decomposition dental resins free-radical polymerization mechanochemistry methyl-methacrylate oxygen inhibition peroxide photopolymerization
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https://hal-amu.archives-ouvertes.fr/hal-01774254
Contributor : Marlene Delhaye <>
Submitted on : Monday, April 23, 2018 - 3:01:06 PM
Last modification on : Wednesday, July 15, 2020 - 11:52:04 AM

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P. Garra, F. Dumur, A. Al Mousawi, B. Graff, D. Gigmes, et al.. Mechanosynthesized copper(I) complex based initiating systems for redox polymerization: towards upgraded oxidizing and reducing agents. Polymer Chemistry, Royal Society of Chemistry - RSC, 2017, 8 (38), pp.5884--5896. ⟨10.1039/c7py01244f⟩. ⟨hal-01774254⟩

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