Conversion of the cluster [Os3(CHCFc)(CO)10] (CHCFc = ethynylferrocene) into [Os3(S)(CHCFc)(CO)9] by reaction with sulphur. Crystal structures of these clusters and of [Os3H(C2Fc)(CO)9]

Kenneth Hardcastle (1) , Antony Deeming (2) , Didier Nuel (3) , Nicholas Powell

1 Department of Chemistry [Emory]
2 UCL - University College of London [London]
3 ISM2 - Institut des Sciences Moléculaires de Marseille

Domaines: Catalyse; Chimie de coordination

Kenneth Hardcastle, Antony Deeming, Didier Nuel, Nicholas Powell. Conversion of the cluster [Os3(CHCFc)(CO)10] (CHCFc = ethynylferrocene) into [Os3(S)(CHCFc)(CO)9] by reaction with sulphur. Crystal structures of these clusters and of [Os3H(C2Fc)(CO)9]. Journal of Organometallic Chemistry, 1989, 375 (2), pp.217 - 232. ⟨10.1016/0022-328X(89)85116-2⟩. ⟨hal-01838241⟩