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Room-Temperature Characterization of a Mixed-Valent μ-Hydroxodicopper(II,III) Complex

Abstract : Bis(μ-hydroxo)dicopper(II,II) bearing a naphthyridine-based ligand has been synthesized and characterized in the solid state and solution. Cyclic voltammetry at room temperature displays a reversible redox system that corresponds to the monoelectronic oxidation of the complex. Spectroscopic and time-resolved spectroelectrochemical data coupled to theoretical results support the formation of a charge-localized mixed-valent CuII,III2 species.
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https://hal.archives-ouvertes.fr/hal-01948813
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Submitted on : Saturday, December 8, 2018 - 6:30:32 PM
Last modification on : Friday, August 5, 2022 - 2:38:01 PM

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James Isaac, Federica Gennarini, Isidoro López, Aurore Thibon-Pourret, Rolf David, et al.. Room-Temperature Characterization of a Mixed-Valent μ-Hydroxodicopper(II,III) Complex. Inorganic Chemistry, American Chemical Society, 2016, 55 (17), pp.8263-8266. ⟨10.1021/acs.inorgchem.6b01504⟩. ⟨hal-01948813⟩

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