Journal articles
Experimental and theoretical studies of (4 + 1) annulations between α‐oxoketenes and stable phosphorous, nitrogen, or sulfur ylides
Abstract : α Oxoketenes generated in situ by a microwave assisted Wolff rearrangement-at 170°C were found to react with stabilized sulfur ylides in (4 + 1) annulation processesto afford functionalized 3 hydroxyfurans.-Theoretical mechanistic investigations revealed that the reaction proceeds in two steps via a short-lived betaine intermediate, a general feature of the reactions of α oxoketenes-with stable phosphorous, nitrogen, and sulfur ylides.
Cited literature [19 references]
https://hal-amu.archives-ouvertes.fr/hal-02059903
Contributor : Yannick Carissan Connect in order to contact the contributor
Submitted on : Thursday, March 7, 2019 - 9:29:21 AM
Last modification on : Sunday, June 26, 2022 - 2:37:02 AM
Long-term archiving on: : Monday, June 10, 2019 - 4:29:07 PM
Contributor : Yannick Carissan Connect in order to contact the contributor
Submitted on : Thursday, March 7, 2019 - 9:29:21 AM
Last modification on : Sunday, June 26, 2022 - 2:37:02 AM
Long-term archiving on: : Monday, June 10, 2019 - 4:29:07 PM
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2019JPOC-asap-(4+1)-oxoketene-...
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