Skip to Main content Skip to Navigation
Journal articles

Binuclear copper(II) complexes 1: Synthesis, characterization and evaluation of a new complex in phosphatase-like activity

Abstract : A new binuclear Cu(II) complex derived from a pamoic type ligand has been synthesized and characterized by X-ray crystallography. This complex was checked as catalysts in the hydrolysis of bis(p-nitro-phenyl)phosphate. Its catalytic properties were studied at various pH and compared to the mononuclear Cu(II) complex. At pH 5.38, the binuclear Cu(II) complex exhibited a phosphatase-like activity with 11 TON and 24% conversion and was found to be 41-fold more active than the mononuclear counterpart.
Document type :
Journal articles
Complete list of metadata

Cited literature [32 references]  Display  Hide  Download

https://hal.archives-ouvertes.fr/hal-02091433
Contributor : Jalila SIMAAN Connect in order to contact the contributor
Submitted on : Tuesday, April 9, 2019 - 11:00:50 AM
Last modification on : Tuesday, December 14, 2021 - 8:36:13 AM

Identifiers

Collections

Citation

Olivier Schicke, Bruno Faure, Michel Giorgi, A. Jalila Simaan, Marius Réglier. Binuclear copper(II) complexes 1: Synthesis, characterization and evaluation of a new complex in phosphatase-like activity. Inorganica Chimica Acta Reviews, Elsevier, 2012, 391, pp.189-194. ⟨10.1016/j.ica.2012.04.019⟩. ⟨hal-02091433⟩

Share

Metrics

Record views

36