Acridone derivatives as high performance visible light photoinitiators for cationic and radical photosensitive resins for 3D printing technology and for low migration photopolymer property

Abdallah Mira; Huong Le; Akram Hijazi; Michael Schmitt; Bernadette Graff; Frédéric Dumur; Thanh-Tuan Bui; Fabrice Goubard; Jean-Pierre Fouassier; Jacques Lalevee

doi:10.1016/j.polymer.2018.11.021

Journal articles

Acridone derivatives as high performance visible light photoinitiators for cationic and radical photosensitive resins for 3D printing technology and for low migration photopolymer property

Abdallah Mira ¹ Huong Le ² Akram Hijazi ³ Michael Schmitt ^{1, 4} Bernadette Graff ¹ Frédéric Dumur ⁵ Thanh-Tuan Bui ² Fabrice Goubard ² Jean-Pierre Fouassier ¹ Jacques Lalevee ¹

1 IS2M - Institut de Science des Matériaux de Mulhouse

2 LPPI - Laboratoire de Physico-chimie des Polymères et des Interfaces

3 Université Libanaise

4 UNISTRA - Université de Strasbourg

5 ICR - Institut de Chimie Radicalaire

Abstract : This paper is devoted to study two acridone derivatives (A-2DPA and A-2PTz). These acridone compounds are synthesized and proposed as high performance visible light photoinitiators, in the presence of an iodonium salt or/and an amine (NPG or EDB), for both the free radical polymerization of (meth)acrylates and the cationic polymerization of epoxides upon irradiation with LED@405 nm. Excellent polymerization initiating abilities are found, and high final monomer conversions are obtained. A full picture of the involved photochemical mechanisms is provided. This paper is also concerned with the use of these acridone-based systems in new 3D printing resins. Finally, the usage of the new acridone derivatives for photopolyrners with low migration properties is particularly outlined.

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Journal articles

Domain :

Chemical Sciences

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Submitted on : Saturday, April 6, 2019 - 5:16:28 PM
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Acridone derivatives as high performance visible light photoinitiators for cationic and radical photosensitive resins for 3D printing technology and for low migration photopolymer property

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Acridone derivatives as high performance visible light photoinitiators for cationic and radical photosensitive resins for 3D printing technology and for low migration photopolymer property

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