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Radical polymerization of radical-labeled monomers: The triarylmethyl-based radical monomer as an example

Mariya V. Edeleva 1, 2 Sylvain R.A. Marque 3, 4 Olga Yu Rogozhnikova 1, 2 Victor M. Tormyshev 1, 2 Tatiana I. Troitskaya 2 Elena G. Bagryanskaya 1, 2
1 NSU - Novosibirsk State University
2 N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry
3 ICR - Institut de Chimie Radicalaire
4 RAS, SB, NN - Vorozhtsov Novosibirsk Institute of Organic Chemistry
Abstract : Recent development of spin-labeled nitroxide-mediated polymerization (NMP) involving successful polymer preparation with high livingness and narrow dispersity in the presence of persistent trityl-based stable radicals attached to the initiators (90% recovery of a trityl radical signal after the polymerization) led us to the preparation of stable organic radical polymers based on trityl radical-substituted monomers using NMP as the method of polymerization despite the claims in the literature about its expected failure. Here, we present successful radical polymerization and NMP of a trityl radical-based tri- and mono-monomer yielding more than 90% recovery of the trityl radical signal. (c) 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018, 56, 2656-2664
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https://hal-amu.archives-ouvertes.fr/hal-02091876
Contributor : Didier Gigmes <>
Submitted on : Saturday, April 6, 2019 - 5:16:39 PM
Last modification on : Tuesday, October 13, 2020 - 3:10:54 AM

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Mariya V. Edeleva, Sylvain R.A. Marque, Olga Yu Rogozhnikova, Victor M. Tormyshev, Tatiana I. Troitskaya, et al.. Radical polymerization of radical-labeled monomers: The triarylmethyl-based radical monomer as an example. Journal of Polymer Science Part A: Polymer Chemistry, Wiley, 2018, 56 (23), pp.2656--2664. ⟨10.1002/pola.29249⟩. ⟨hal-02091876⟩

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