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Nitroxide Radicals with Cucurbit[n]urils and Other Cavitands

Abstract : The interface of nitroxide radicals with cucurbit[n]urils (CB[n]) is covered in this review. Either used as spin probes, spin labels, or stoppers for paramagnetic rotaxanes, nitroxides offer new opportunities to investigate CB[n] and their inclusion complexes, especially thanks to EPR spectroscopy. On the other hand, CB[n] also offer interesting opportunities to modulate nitroxide properties such as protection or structuring. The multiple back and forth between the two well-established areas where nitroxides bring information about CB[n], and CB[n] modulate nitroxide properties, have enabled to shed some light at this new interesting interface.
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Submitted on : Saturday, April 6, 2019 - 5:18:18 PM
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Olivier Ouari, David Bardelang. Nitroxide Radicals with Cucurbit[n]urils and Other Cavitands. Israel Journal of Chemistry, Wiley-VCH Verlag, 2018, 58 (3-4), pp.343--356. ⟨10.1002/ijch.201700115⟩. ⟨hal-02091917⟩



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