Skip to Main content Skip to Navigation
Journal articles

Imidazoline and imidazolidine nitroxides as controlling agents in nitroxide-mediated pseudoliving radical polymerization

Mariya V. Edeleva 1, 2 Sylvain Marque 3 Elena G. Bagryanskaya 1, 2
1 NSU - Novosibirsk State University
2 N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry
3 ICR - Institut de Chimie Radicalaire
Abstract : Controlled, or pseudoliving, radical polymerization provides unique opportunities for the synthesis of structurally diverse polymers with a narrow molecular -weight distribution. These reactions occur under relatively mild conditions with broad tolerance to functional groups in the monomers. The nitroxide-mediated pseudoliving radical polymerization is of particular interest for the synthesis of polymers for biomedical applications. This review briefly describes one of the mechanisms of controlled radical polymerization. The studies dealing with the use of imidazoline and imidazolidine nitroxides as controlling agents for nitroxide-mediated pseudoliving radical polymerization of various monomers are summarized and analyzed. The publications addressing the key steps of the controlled radical polymerization in the presence of imidazoline and imidazolidine nitroxides and new approaches to nitroxide-mediated polymerization based on protonation of both nitroxides a nd monomers are considered.
Document type :
Journal articles
Complete list of metadata
https://hal-amu.archives-ouvertes.fr/hal-02091926
Contributor : Didier Gigmes Connect in order to contact the contributor
Submitted on : Saturday, April 6, 2019 - 5:18:40 PM
Last modification on : Wednesday, October 27, 2021 - 1:39:33 PM

Identifiers

Collections

UNIV-AMU | CNRS | INC-CNRS | USPC

`

Citation

Mariya V. Edeleva, Sylvain Marque, Elena G. Bagryanskaya. Imidazoline and imidazolidine nitroxides as controlling agents in nitroxide-mediated pseudoliving radical polymerization. Russian Chemical Reviews, 2018, 87 (4), pp.328--349. ⟨10.1070/RCR4765⟩. ⟨hal-02091926⟩

Export

BibTeX TEI DC DCterms EndNote

Share

Metrics

Record views

34