ECM - Ecole Centrale de Marseille : UMR7313 (Pôle de l'étoile, Technopole de Château-Gombert, 38 rue Frédéric Joliot-Curie, 13013 Marseille, France - France)
Abstract : 3D printing technology is increasingly used in flow analysis, to develop low cost and tailor-made devices. The possibility of grafting specific molecules onto 3D printed parts offers new perspectives for the development of flow systems. In this study, a MPFS system including a dicarboxylate 1,5-diphenyl-3-thiocarbazone grafted 3D-printed device has been developed for mercury determination. For this purpose, the surface of 3D-printed cuboids was first modified with amine functional groups and then grafted with dicarboxylate 1,5-diphenyl-3-thiocarbazone. This new grafted device resulted in selective mercury preconcentration with extraction and elution yields higher than 90% even at high sampling flow rates. The detection can then be carried out in two ways: a direct detection of mercury extracted onto 3D-printed grafted cuboids by atomic absorption spectrophotometry after amalgam on gold or a detection of mercury in solution after elution with L-cysteine by spectrophotometry or cold vapor atomic absorption spectrometry.
https://hal-amu.archives-ouvertes.fr/hal-02284950
Contributor : Bruno Coulomb
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Submitted on : Thursday, September 12, 2019 - 12:27:25 PM
Last modification on : Monday, September 16, 2019 - 2:01:31 PM
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until : 2020-11-15
