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Recent developments in enantioselective zinc-catalyzed transformations

Abstract : This review collects the recent advances in the field of enantioselective zinc-catalyzed transformations, covering the literature since the beginning of 2015, illustrating the power of chiral green zinc catalysts to promote all types of reactions. A range of highly enantioselective reactions have been developed in the last six years, including cycloadditions, alkynylation/allylation reactions of carbonyl compounds and derivatives, additions of diorganozincs to carbonyl compounds and derivatives, Mannich reactions, (nitro)aldol reactions, other 1,2-nucleophilic additions to carbonyl compounds and derivatives, Michael additions, Friedel-Crafts reactions, reductions, a-functionalizations of carbonyl compounds, ringopening reactions, epoxidations, halolactonizations, domino/tandem reactions and miscellaneous reactions.
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https://hal.archives-ouvertes.fr/hal-03205980
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Submitted on : Thursday, April 22, 2021 - 5:40:06 PM
Last modification on : Sunday, June 26, 2022 - 3:07:38 AM

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Hélène Pellissier. Recent developments in enantioselective zinc-catalyzed transformations. Coordination Chemistry Reviews, Elsevier, 2021, 439, pp.213926. ⟨10.1016/j.ccr.2021.213926⟩. ⟨hal-03205980⟩

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