Journal articles
Guest Exchange by a Partial Energy Ratchet in Water
Abstract : Molecular machines are ubiquitous in nature and function away from equilibrium by consuming fuels to produce appropriate work. Chemists have recently excelled at mimicking the fantastic job performed by natural molecular machines with synthetic systems soluble in organic solvents. In efforts toward analogous systems working in water, we show that guest molecules can be exchanged in the synthetic macrocycle cucurbit[7]uril by involving kinetic traps, and in such a way as modulating energy wells and kinetic barriers using pH, light and redox stimuli. Ditolyl-viologen can also be exchanged using the best kinetic trap and interfaced with alginate thus affording pH-responsive blue, fluorescent hydrogels. With tunable rate and binding constants toward relevant guests, cucurbiturils may become excellent ring molecules for the construction of advanced molecular machines working in water.
https://hal-amu.archives-ouvertes.fr/hal-03227446
Contributor : Emilie Pepe Connect in order to contact the contributor
Submitted on : Friday, May 28, 2021 - 10:05:09 AM
Last modification on : Monday, November 22, 2021 - 5:20:03 PM
Long-term archiving on: : Sunday, August 29, 2021 - 6:03:09 PM
Contributor : Emilie Pepe Connect in order to contact the contributor
Submitted on : Friday, May 28, 2021 - 10:05:09 AM
Last modification on : Monday, November 22, 2021 - 5:20:03 PM
Long-term archiving on: : Sunday, August 29, 2021 - 6:03:09 PM
File
manuscript pour depot dans HA...
Files produced by the author(s)