Journal articles
Triple Stack of a Viologen Derivative in a CB[10] Pair
Fengbo Liu
1
Shagor Chowdhury
2
Roselyne Rosas
3
Valérie Monnier
3
Laurence Charles
4
Hakim Karoui
4
Didier Gigmes
4
Olivier Ouari
4
Floris Chevallier
2
Christophe Bucher
2
Anthony Kermagoret
4
Simin Liu
1
David Bardelang
4
Floris Chevallier 2
Author
Christophe Bucher 2
Author IdHAL : christophe-bucher ORCID : https://orcid.org/0000-0003-1803-6733
Anthony Kermagoret 4
Author
Simin Liu 1
Author
David Bardelang 4
Author IdHAL : david-bardelang ORCID : https://orcid.org/0000-0002-0318-5958
2
LC - Laboratoire de Chimie - UMR5182 (Ens de Lyon, Site Jacques Monod - 46 allée d'Italie - 69364 Lyon cedex 07 - France)
- CNRS - Centre National de la Recherche Scientifique : UMR5182 (France)
- UCBL - Université Claude Bernard Lyon 1 (43, boulevard du 11 novembre 1918, 69622 Villeurbanne cedex - France)
- Université de Lyon (92 rue Pasteur - CS 30122, 69361 Lyon Cedex 07 - France)
- ENS Lyon - École normale supérieure - Lyon (15 parvis René Descartes - BP 7000 - 69342 Lyon Cedex 07 - France)
- INC - Institut de Chimie du CNRS (3 Rue Michel-Ange 75 016 Paris - France)
3
AMU SPEC - Spectropôle - Aix Marseille Université (Spectropole - Aix-Marseille Université
Campus Scientifique de Saint Jérôme
Service 511
13397 Marseille cedex 20 - France)
- CNRS - Centre National de la Recherche Scientifique : UMR6517 (France)
- AMU - Aix Marseille Université (Aix-Marseille Université Jardins du Pharo 58 Boulevard Charles Livon 13284 Marseille cedex 7 - France)
4
ICR - Institut de Chimie Radicalaire (Avenue Escadrille Normandie-Niemen
Service D42
13397 Marseille cedex 20 - France)
- INC - Institut de Chimie du CNRS (3 Rue Michel-Ange 75 016 Paris - France)
- CNRS - Centre National de la Recherche Scientifique : UMR7273 (France)
- AMU - Aix Marseille Université : UMR7273 (Aix-Marseille Université Jardins du Pharo 58 Boulevard Charles Livon 13284 Marseille cedex 7 - France)
Abstract : A viologen–phenylene–imidazole (VPI) conjugate, previously shown to be singly complexed by CB[7] and doubly bound by CB[8], is herein shown to form antiparallel triple stacks in water with cucurbit[10]uril (CB[10]), pairwise complexing the guest trimer. The quinary host:guest 2:3 complex showed features assignable to charge-transfer interactions. Under reductive conditions, CB[10] could solubilize a VPI radical, even though CB[10] and reduced VPI are almost insoluble, thereby illustrating a possible new application for CB[10].
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Journal articles
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https://hal-amu.archives-ouvertes.fr/hal-03227458
Contributor : Emilie Pepe Connect in order to contact the contributor
Submitted on : Monday, May 17, 2021 - 12:10:14 PM
Last modification on : Wednesday, May 11, 2022 - 1:18:34 PM
Long-term archiving on: : Wednesday, August 18, 2021 - 6:30:21 PM
Contributor : Emilie Pepe Connect in order to contact the contributor
Submitted on : Monday, May 17, 2021 - 12:10:14 PM
Last modification on : Wednesday, May 11, 2022 - 1:18:34 PM
Long-term archiving on: : Wednesday, August 18, 2021 - 6:30:21 PM
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triplestack.pdf
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- HAL Id : hal-03227458, version 1
- DOI : 10.1021/acs.orglett.1c00773
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UNIV-AMU | ENS-LYON | INC-CNRS | CNRS | UDL | UNIV-LYON1 | HAL-CHIMIE-ENSLYON
Citation
Fengbo Liu, Shagor Chowdhury, Roselyne Rosas, Valérie Monnier, Laurence Charles, et al.. Triple Stack of a Viologen Derivative in a CB[10] Pair. Organic Letters, American Chemical Society, 2021, ⟨10.1021/acs.orglett.1c00773⟩. ⟨hal-03227458⟩
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