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Selecting one out of six stereoisomers

Abstract : The design of an original molecular architecture featuring an unusual sterically congested C(sp2)–C(sp3) stereogenic axis with six high rotational barriers results in the formation of six different stereoisomers. The configuration of this axis can be controlled by transition metal catalysis and one out of six stereoisomers can be produced selectively.
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https://hal.archives-ouvertes.fr/hal-03278289
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Submitted on : Monday, July 5, 2021 - 2:27:39 PM
Last modification on : Sunday, June 26, 2022 - 3:10:40 AM
Long-term archiving on: : Wednesday, October 6, 2021 - 6:33:58 PM

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Damien Bonne, Jean Rodriguez. Selecting one out of six stereoisomers. Nature Catalysis, Nature Publishing Group, 2021, 4 (6), pp.451-452. ⟨10.1038/s41929-021-00639-5⟩. ⟨hal-03278289⟩

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