Radioactive decay of $\mathrm {{}^{90}Sr}$ in cement: a non-equilibrium first-principles investigation

Jorge Kohanoff (1) , Alfredo Correa (2) , Gleb Gribakin (1) , Conrad Johnston (1) , Andrés Saúl (3)

1 QUB - Queen's University [Belfast]
2 LLNL - Lawrence Livermore National Laboratory
3 CINaM - Centre Interdisciplinaire de Nanoscience de Marseille

Cement is an inexpensive and relatively easily manageable material that is used as a last barrier for nuclear waste disposal. Under these conditions, the cement is in contact with low radiation doses, but there is a distinct possibility of being contaminated with radioactive products. Of particular concern is the medium lived half-life product $\mathrm {{}^{90}}$Sr (28.8 years) due to its ability to replace Ca. $\mathrm {{}^{90}}$Sr undergoes $\beta $-decay to $\mathrm {{}^{90}}$Y which, in turn, $\beta $-decays to stable $\mathrm {{}^{90}}$Zr . In this work, we discuss systematically the chain of non-equilibrium processes that result as a consequence of $\beta$-decay events in cement. We first use density functional-based methods to study the consequences of the sudden increase of the nuclear charge from $Z$ to $Z+1$, a possible induced ionization and the perturbation of the surrounding electronic charge. Secondly, we use molecular dynamics simulations to study the recoil of the daughter nucleus. Finally, we discuss the damage caused by the ionization cascade produced during the propagation of the $\beta $-electron and the resulting chemical and structural perturbation. Graphic Abstract

Domains: Physics [physics]; Condensed Matter [cond-mat]

Jorge Kohanoff, Alfredo Correa, Gleb Gribakin, Conrad Johnston, Andrés Saúl. Radioactive decay of $\mathrm {{}^{90}Sr}$ in cement: a non-equilibrium first-principles investigation. The European Physical Journal D : Atomic, molecular, optical and plasma physics, 2021, 75 (9), ⟨10.1140/epjd/s10053-021-00202-8⟩. ⟨hal-03358070⟩