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Article Dans Une Revue Chemistry - A European Journal Année : 2021

Luminescent chiral exciplexes with sky-blue and green circularly polarized-thermally activated delayed fluorescence

Résumé

Luminescent exciplexes based on a chiral electron donor and achiral acceptors are reported as a new approach to design circularly polarized (CP) and thermally activated delayed fluorescence (TADF) emitters. This strategy results in rather high CP luminescence (CPL) values with g$_{lum}$ up to 7x10$^{-3}$, one order of magnitude higher in comparison to the CPL signal recorded for the chiral donor alone g$_{lum}$ similar to 7x10$^{-4}$. This increase occurs concomitantly with a CPL sign inversion, as a result of the strong charge-transfer emission character, as experimentally and theoretically rationalized by using a covalent chiral donor-acceptor model. Interestingly, blue, green-yellow and red chiral luminescent exciplexes can be obtained by modifying with the electron accepting character of the achiral unit while keeping the same chiral donor unit. These results bring new (inter)molecular guidelines to obtain simply and efficiently multi-color CP-TADF emitters.
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Dates et versions

hal-03413973 , version 1 (10-11-2021)

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Patthira Sumsalee, Laura Abella, Sitthichok Kasemthaveechok, Nicolas Vanthuyne, Marie Cordier, et al.. Luminescent chiral exciplexes with sky-blue and green circularly polarized-thermally activated delayed fluorescence. Chemistry - A European Journal, 2021, 27 (66), pp.16505-16511. ⟨10.1002/chem.202102765⟩. ⟨hal-03413973⟩
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