Enantioselective synthesis of chiral porphyrin macrocyclic hosts and kinetic enantiorecognition of viologen guests

Pieter J Gilissen (1) , Annemiek D Slootbeek (1) , Jiangkun Ouyang (1) , Nicolas Vanthuyne (2) , Rob Bakker (1) , Johannes a a W Elemans (1) , Roeland J M Nolte (1)

1 Institute for Molecules and Materials [Nijmegen]
2 ISM2 - Institut des Sciences Moléculaires de Marseille

Chiral guests display kinetic stereoselective threading through chiral porphyrin cages if their chirality is located at the chain ends and not in the centers, supporting the previously reported entron effect of threading.

Domaines: Chimie

Pieter J Gilissen, Annemiek D Slootbeek, Jiangkun Ouyang, Nicolas Vanthuyne, Rob Bakker, et al.. Enantioselective synthesis of chiral porphyrin macrocyclic hosts and kinetic enantiorecognition of viologen guests. Chemical Science, 2021, 12 (5), pp.1661-1667. ⟨10.1039/d0sc05233g⟩. ⟨hal-03516900⟩