Thiophene fused indenocorannulenes: synthesis, variable emission, and exceptional chiral configurational stability

Xiaoqi Tian (1) , Suchaya Chaiworn (1) , Jun Xu (1) , Nicolas Vanthuyne (2) , Kim K Baldridge (1) , Jay S Siegel (1)

1 TJU - Tianjin University
2 ISM2 - Institut des Sciences Moléculaires de Marseille

Graph theory and isosteric replacement leads to the design and synthesis of (chiral) thiophene-fused indenocorannulenes with exceptional configurational stability and possible use as chiral catalysts, chiroptical materials, and sensors.

Domaines: Chimie

Xiaoqi Tian, Suchaya Chaiworn, Jun Xu, Nicolas Vanthuyne, Kim K Baldridge, et al.. Thiophene fused indenocorannulenes: synthesis, variable emission, and exceptional chiral configurational stability. Organic Chemistry Frontiers, 2021, 8 (14), pp.3653-3658. ⟨10.1039/d1qo00596k⟩. ⟨hal-03516904⟩