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On-Surface Synthesis: A New Route Realizing Single-Layer Conjugated Metal–Organic Structures

Abstract : Recently, both experimental and theoretical advances have demonstrated that two-dimensional conjugated metal–organic frameworks (2D-cMOFs) exhibit interesting electronic and magnetic properties, such as high conductivity and ferromagnetism. Theoretical studies have predicted that exotic quantum states, including topological insulating states and superconductivity, emerge in some 2D-MOFs. The high design tunability of MOFs’ structure and composition provides great opportunities to realize these structures. However, most conventional synthesis methods yield multilayer structures of the 2D-cMOFs, in which the predicted exotic quantum phases are often quenched because of interlayer interactions. It is highly desirable to synthesize single-layer cMOFs. On-surface synthesis represents a novel strategy toward this goal. In this Perspective, we discuss the recent developments in on-surface synthesis of 1D- and 2D-cMOFs.
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Contributor : Mathieu Abel Connect in order to contact the contributor
Submitted on : Tuesday, March 15, 2022 - 2:41:27 PM
Last modification on : Friday, April 22, 2022 - 9:22:05 AM


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Jing Liu, Mathieu Abel, Nian Lin. On-Surface Synthesis: A New Route Realizing Single-Layer Conjugated Metal–Organic Structures. Journal of Physical Chemistry Letters, American Chemical Society, 2022, 13 (5), pp.1356-1365. ⟨10.1021/acs.jpclett.1c04134⟩. ⟨hal-03604579⟩



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