N-Heterocyclic Carbene-Mediated Organocatalytic Transfer of Tin onto Aldehydes: New Access to alpha-Silyloxyalkylstannanes and gama-Silyloxyallylstannanes

Romain Blanc (1) , Laurent Commeiras (1) , Jean-Luc Parrain (1)

1 STeRéO

A new, highly and mild efficient N-heterocyclic carbene (NHC) organocatalytic procedure for the transfer of tin from Bu3Sn-SiMe3 onto aldehydes for the preparation of α-silyloxyalkylstannanes and γ-silyloxyallylstannanes

Mots clés: Organocatalytic; N-Heterocyclic carbenes; α-silyloxyalkylstannanes; γ-silyloxyallylstannanes

Domaines: Chimie organique

Romain Blanc, Laurent Commeiras, Jean-Luc Parrain. N-Heterocyclic Carbene-Mediated Organocatalytic Transfer of Tin onto Aldehydes: New Access to alpha-Silyloxyalkylstannanes and gama-Silyloxyallylstannanes. Advanced Synthesis and Catalysis, 2010, 352, pp.661-666. ⟨10.1002/adsc.200900816⟩. ⟨hal-00678940⟩