Journal articles
Catalyst- and Halogen-Free Regioselective Friedel-Crafts alpha-Ketoacylations
Abstract : Highly regio- selective and efficient catalyst- and halogen-free Friedel-Crafts alpha-ketoacy- lation reactions leading to heterocycles functionalized with a very versatile 1,3- diketone moiety are described. The reactions rely on microwave-assisted domino Wolff rearrangement/Friedel- Crafts sequences from 2-diazo-1,3- diketones via transient, highly reactive alpha-keto ketene intermediates.
https://hal.archives-ouvertes.fr/hal-00736640
Contributor : Gaelle Chouraqui Connect in order to contact the contributor
Submitted on : Friday, September 28, 2012 - 4:49:00 PM
Last modification on : Tuesday, December 14, 2021 - 8:36:12 AM
Contributor : Gaelle Chouraqui Connect in order to contact the contributor
Submitted on : Friday, September 28, 2012 - 4:49:00 PM
Last modification on : Tuesday, December 14, 2021 - 8:36:12 AM
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