HAL will be down for maintenance from Friday, June 10 at 4pm through Monday, June 13 at 9am. More information
Skip to Main content Skip to Navigation
Journal articles

Rational design of dinitroxide biradicals for efficient cross-effect dynamic nuclear polarization

Dominik Kubicki 1 Gilles Casano 2 Martin Schwarzwälder 3 Sebastien Abel 2 Claire Sauvée 2 Karthikeyan Ganesan 4 Maxim Yulikov 3 Aaron Rossini 5 Gunnar Jeschke 6 Christophe Copéret 3 Anne Lesage 1 Paul Tordo 7 Olivier Ouari 2 Lyndon Emsley 5
1 Solid-State NMR Methods for Materials - Méthodes de RMN à l'état solide pour les matériaux
ISA - Institut des Sciences Analytiques
2 ICR - Institut de Chimie Radicalaire
3 Laboratory of Inorganic Chemistry
4 Association of Computer Electronics and Electrical Engineers (ACEEE)
5 EPFL - Ecole Polytechnique Fédérale de Lausanne
6 Laboratory of Physical Chemistry
7 SREP - Structure et Réactivité des Espèces Paramagnétiques
Abstract : A series of 37 dinitroxide biradicals have been prepared and their performance studied as polarizing agents in cross-effect DNP NMR experiments at 9.4 T and 100 K in 1,1,2,2-tetrachloroethane (TCE). We observe that in this regime the DNP performance is strongly correlated with the substituents on the polarizing agents, and electron and nuclear spin relaxation times, with longer relaxation times leading to better enhancements. We also observe that deuteration of the radicals generally leads to better DNP enhancement but with longer build-up time. One of the new radicals introduced here provides the best performance obtained so far under these conditions.
Document type :
Journal articles
Complete list of metadata

Cited literature [57 references]  Display  Hide  Download
https://hal-amu.archives-ouvertes.fr/hal-01387080
Contributor : Emilie Pepe Connect in order to contact the contributor
Submitted on : Tuesday, October 25, 2016 - 10:34:36 AM
Last modification on : Tuesday, December 14, 2021 - 8:42:06 AM

File

Vignette du document
chemscience2016.7.550-558.pdf
Publisher files allowed on an open archive

Identifiers

Collections

UNIV-AMU | CNRS | ISA | INC-CNRS | UNIV-LYON1 | UDL

Citation

Dominik Kubicki, Gilles Casano, Martin Schwarzwälder, Sebastien Abel, Claire Sauvée, et al.. Rational design of dinitroxide biradicals for efficient cross-effect dynamic nuclear polarization. Chemical Science , The Royal Society of Chemistry, 2016, 7 (1), pp.550 - 558. ⟨10.1039/C5SC02921J⟩. ⟨hal-01387080⟩

Export

BibTeX TEI DC DCterms EndNote Datacite

Share

Metrics

Record views

273

Files downloads

307