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A Robust Infinite Zirconium Phenolate Building Unit to Enhance the Chemical Stability of Zr MOFs

Georges Mouchaham 1 Lucy Cooper 1 Nathalie Guillou 1 Charlotte Martineau 1 Erik Elkaïm 2 Sandrine Bourrelly 3 Philip L. Llewellyn 3 Clémence Allain 4 Gilles Clavier 4 Christian Serre 1 Thomas Devic 1 
1 ILV - Institut Lavoisier de Versailles
2 SSOLEIL - Synchrotron SOLEIL
3 MADIREL - Matériaux divisés, interfaces, réactivité, électrochimie
4 PPSM - Laboratoire de Photophysique et Photochimie Supramoléculaires et Macromoléculaires
Abstract : A novel Zr-chain based MOF, namely MIL-163, was designed and successfully synthesized using a bis-1,2,3-trioxobenzene ligand. Endowed with large square-shaped channels of 12 angstrom width, it shows remarkable water uptake (ca. 0.6cm(3)g(-1) at saturating vapor pressure) and a remarkable stability in simulated physiological media, where archetypical Zr carboxylate MOFs readily degrade.
Keywords : METAL-ORGANIC FRAMEWORKS COORDINATION POLYMERS WATER-ADSORPTION FUNCTIONALIZATION TOPOLOGY CAPTURE PORES CO2
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https://hal-amu.archives-ouvertes.fr/hal-01416642
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Submitted on : Wednesday, December 14, 2016 - 4:42:19 PM
Last modification on : Friday, April 8, 2022 - 6:10:02 PM

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CNRS | UNIV-AMU | ENS-CACHAN | UVSQ | INC-CNRS | ILV | MADIREL | UNIV-PARIS-SACLAY | SYNCHROTRON-SOLEIL | CMM | ENS-PARIS-SACLAY | GS-CHIMIE | INSTITUT-SCIENCES-LUMIERE

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Georges Mouchaham, Lucy Cooper, Nathalie Guillou, Charlotte Martineau, Erik Elkaïm, et al.. A Robust Infinite Zirconium Phenolate Building Unit to Enhance the Chemical Stability of Zr MOFs. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2015, 54 (45), pp.13297 - 13301. ⟨10.1002/anie.201507058⟩. ⟨hal-01416642⟩

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