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TDAE Strategy for the Synthesis of 2,3-Diaryl N-Tosylaziridines

Abstract : We report herein an original and rapid synthesis of 2,3-diaryl N-tosylaziridines by TDAE strategy starting from ortho-or para-nitro(dichloromethyl)benzene derivatives and N-tosylimines. A mixture of cis/trans isomers was isolated from 1-(dichloromethyl)-4-nitrobenzene, whereas only trans-aziridines were obtained from ortho-nitro derivatives.
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https://hal-amu.archives-ouvertes.fr/hal-01425540
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Submitted on : Tuesday, January 3, 2017 - 4:00:37 PM
Last modification on : Wednesday, December 12, 2018 - 2:52:05 PM
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Omar Khoumeri, Cédric Spitz, Thierry Terme, Patrice Vanelle. TDAE Strategy for the Synthesis of 2,3-Diaryl N-Tosylaziridines. Molecules, MDPI, 2013, 2013, pp.7364 - 7375. ⟨10.3390/molecules18077364⟩. ⟨hal-01425540⟩

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