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Mild and Metal-Free Diastereoselective Synthesis of N-tert-Butanesulfinylamines by Using Tetrakis(dimethylamino)ethylene

Abstract : A mild and metal-free diastereoselective synthesis of N-tert-butanesulfinylamines was developed by using a strategy based on tetrakis(dimethylamino)ethylene. Good yields and diastereoselectivities were achieved by addition of o-nitrobenzyl chloride or 4-[4-(chloromethyl)phenyl]-1,2-dimethyl-5-nitro-1H-imidazole to readily available N-tert-butanesulfinimines.
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https://hal-amu.archives-ouvertes.fr/hal-01425582
Contributor : Cédric Spitz Connect in order to contact the contributor
Submitted on : Tuesday, January 3, 2017 - 4:16:15 PM
Last modification on : Tuesday, October 19, 2021 - 10:49:46 PM
Long-term archiving on: : Tuesday, April 4, 2017 - 2:39:21 PM

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Cédric Spitz, Anna Lin, Thierry Terme, Patrice Vanelle. Mild and Metal-Free Diastereoselective Synthesis of N-tert-Butanesulfinylamines by Using Tetrakis(dimethylamino)ethylene. SYNTHESIS, Georg Thieme Verlag, 2014, ⟨10.1055/s-0034-1378636⟩. ⟨hal-01425582⟩

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