One-pot Crabbe homologation-radical cascade cyclisation with memory of chirality

Shovan Mondal; Malek Nechab; Nicolas Vanthuyne; Michèle P. Bertrand

doi:10.1039/c2cc17830c

Journal articles

One-pot Crabbe homologation-radical cascade cyclisation with memory of chirality

Shovan Mondal ¹ Malek Nechab ¹ Nicolas Vanthuyne ² Michèle P. Bertrand ¹

1 ICR - Institut de Chimie Radicalaire

2 ISM2 - Institut des Sciences Moléculaires de Marseille

Abstract : The tandem Crabbe homologation-radical rearrangement of terminal enediynes leads, in a one-pot procedure, to the enantioselective synthesis of six- and seven-membered ring alpha-aminoesters bearing a quaternary stereocenter based on the phenomenon of memory of chirality.

Document type :

Journal articles

Domain :

Chemical Sciences

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https://hal-amu.archives-ouvertes.fr/hal-01460405
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Submitted on : Tuesday, February 7, 2017 - 4:39:17 PM
Last modification on : Thursday, January 23, 2020 - 6:22:05 PM

One-pot Crabbe homologation-radical cascade cyclisation with memory of chirality

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One-pot Crabbe homologation-radical cascade cyclisation with memory of chirality

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