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Journal articles

One-pot Crabbe homologation-radical cascade cyclisation with memory of chirality

Shovan Mondal 1 Malek Nechab 1 Nicolas Vanthuyne 2 Michèle P. Bertrand 1
1 ICR - Institut de Chimie Radicalaire
2 ISM2 - Institut des Sciences Moléculaires de Marseille
Abstract : The tandem Crabbe homologation-radical rearrangement of terminal enediynes leads, in a one-pot procedure, to the enantioselective synthesis of six- and seven-membered ring alpha-aminoesters bearing a quaternary stereocenter based on the phenomenon of memory of chirality.
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Submitted on : Tuesday, February 7, 2017 - 4:39:17 PM
Last modification on : Tuesday, December 14, 2021 - 8:42:06 AM

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UNIV-AMU | CNRS | EC-MARSEILLE | INC-CNRS | ISM2

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Shovan Mondal, Malek Nechab, Nicolas Vanthuyne, Michèle P. Bertrand. One-pot Crabbe homologation-radical cascade cyclisation with memory of chirality. Chemical Communications, Royal Society of Chemistry, 2012, 48 (19), pp.2549--2551. ⟨10.1039/c2cc17830c⟩. ⟨hal-01460405⟩

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