Blue and blue–green PhOLEDs prepared with neutral heteroleptic iridium(III) complexes comprising substituted pyridine-1,2,4-triazoles as the ancillary ligands

Frédéric Dumur (1) , Marc Lepeltier (2) , Bernadette Graff (3) , Emmanuel Contal (1) , Guillaume Wantz (4) , Jacques Lalevee (3) , Cédric R. Mayer , Denis Bertin (1) , Didier Gigmes (1)

1 ICR - Institut de Chimie Radicalaire
2 ILV - Institut Lavoisier de Versailles
3 IS2M - Institut de Science des Matériaux de Mulhouse
4 IMS - Laboratoire de l'intégration, du matériau au système

Two neutral heteroleptic iridium(III) complexes bearing substituted pyridine 1,2,4-triazoles as the ancillary ligands have been designed and investigated as emitters for PhOLEDs. Interestingly, blue and blue–green devices were obtained with the two complexes. Best devices were obtained with C1 and reached a maximum brightness of 10,200 cd/m2, a current efficiency of 4.3 cd/A at an operation voltage of 7.9 V while exhibiting the unusual low turn-on voltage of only 2.8 V. UV–visible absorption and photoluminescence spectroscopy as well as the cyclic voltammetry of the two iridium(III) complexes were also investigated.

Keywords: Blue emission; Electroluminescence; Iridium complex; OLED; Phosphorescence; Triazole; Triplet state

Domains: Chemical Sciences

Frédéric Dumur, Marc Lepeltier, Bernadette Graff, Emmanuel Contal, Guillaume Wantz, et al.. Blue and blue–green PhOLEDs prepared with neutral heteroleptic iridium(III) complexes comprising substituted pyridine-1,2,4-triazoles as the ancillary ligands. Synthetic Metals, 2013, 182, pp.13--21. ⟨10.1016/j.synthmet.2013.07.009⟩. ⟨hal-01460452⟩