Photo-induced proton coupled electron transfer from a benzophenone 'antenna' to an isoindoline nitroxide

Jason C. Morris; Liam A. Walsh; Brunell A. Gomes; Didier Gigmes; Kathryn E. Fairfull-Smith; Steven E. Bottle; James P. Blinco

doi:10.1039/c5ra20100d

Journal articles

Photo-induced proton coupled electron transfer from a benzophenone 'antenna' to an isoindoline nitroxide

Jason C. Morris Liam A. Walsh Brunell A. Gomes Didier Gigmes ¹ Kathryn E. Fairfull-Smith Steven E. Bottle James P. Blinco

1 ICR - Institut de Chimie Radicalaire

Abstract : The current study reports the synthesis and properties of a novel isoindoline nitroxide containing a benzophenone chromophore fused into the carbon framework. When exposed to UV light, rather than undergoing traditional benzophenone photochemical pathways, the presence of the nitroxide enables an energy transfer process whereby the nitroxide enters an excited state which induces an efficient hydrogen atom transfer from unactivated alkanes.

Document type :

Journal articles

Domain :

Chemical Sciences

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https://hal-amu.archives-ouvertes.fr/hal-01460639
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Submitted on : Tuesday, February 7, 2017 - 5:36:16 PM
Last modification on : Tuesday, December 14, 2021 - 8:42:06 AM

Photo-induced proton coupled electron transfer from a benzophenone 'antenna' to an isoindoline nitroxide

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Photo-induced proton coupled electron transfer from a benzophenone 'antenna' to an isoindoline nitroxide

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