Abstract : We present herein an extension of the TDAE strategy using original heterocyclic carbaldehyde as electrophiles. We also evaluate the influence of the presence of nitro group on the reactivity. The TDAE-initiated reactions of various halomethyl and gem-dihalomethyl derivatives with non-nitrated carbaldehyde 1 or 2 formed the expected products accompagnied by original rearranged products while the presence of a nitro group just like the carbaldehyde 21 furnished only the expected products in good yields.
https://hal-amu.archives-ouvertes.fr/hal-01460700 Contributor : Didier GigmesConnect in order to contact the contributor Submitted on : Tuesday, February 7, 2017 - 5:51:21 PM Last modification on : Tuesday, December 14, 2021 - 8:42:06 AM