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Using Pressure to Provoke the Structural Transition of Metal–Organic Frameworks

Abstract : hysteresis of intrusion–extrusion of mercury observed in MIL-53(Cr) particles is interpreted as the transition from large-pore to narrow-pore forms of this metal–organic framework (MOF) material, provoked by the isostatic pressure created by mercury around the porous particles. The observed behavior may be qualitatively explained by a simple energetic model and opens possibilities for applications as dampers or molecular springs.
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Isabelle Beurroies, Mohammed Boulhout, Philip L. Llewellyn, Bogdan Kuchta, Gérard Féray, et al.. Using Pressure to Provoke the Structural Transition of Metal–Organic Frameworks. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2010, ⟨10.1002/anie.201003048⟩. ⟨hal-01465940⟩

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