Synthesis and Characterization of Ruffled Phosphorus meso -Ester Corroles

Di Gao (1) , Cloé Azarias (2) , Anthony d'Aléo (3) , Michel Giorgi (4) , Olivier Siri (3) , Teodor Silviu Balaban (1) , Denis Jacquemin (2, 5) , Gabriel Canard (3)

1 ISM2 - Institut des Sciences Moléculaires de Marseille
2 CEISAM - Chimie Et Interdisciplinarité : Synthèse, Analyse, Modélisation
3 CINaM - Centre Interdisciplinaire de Nanoscience de Marseille
4 AMU SPEC - Spectropôle - Aix Marseille Université
5 IUF - Institut universitaire de France

The strong electron-withdrawing character of 5,15-meso-ester groups was demonstrated through the study of four fluorescent hexacoordinate phosphorus(V) meso-substituted corroles, which were characterized by various techniques including single-crystal X-ray diffraction and first-principles calculations. The nature of the remaining meso substituent tunes the physicochemical properties of these phosphorus complexes only slightly but unexpectedly plays a key role in the ruffling of the macrocycle.

Domaines: Chimie

Di Gao, Cloé Azarias, Anthony d'Aléo, Michel Giorgi, Olivier Siri, et al.. Synthesis and Characterization of Ruffled Phosphorus meso -Ester Corroles. European Journal of Inorganic Chemistry, 2017, 2017 (4), pp.780 - 788. ⟨10.1002/ejic.201601172⟩. ⟨hal-01683282⟩