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Journal Articles Chemical Communications Year : 2017

Synthesis of oligoarylacetylenes with defined conjugated sequences using tailor-made soluble polymer supports

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Abstract

Due to their strong tendency to self-aggregate, unfunctionalized oligoarylacetylenes are difficult to synthesize. Here, tailored polystyrene soluble supports, prepared by atom transfer radical polymerization and post-polymerization modification, were tested for preparing sequence-defined oligoarylacetylenes. Controlled aromatic sequences were obtained by iterative Sonogarisha coupling, using phenyl- and pyridine-based building-blocks.
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hal-01774186 , version 1 (23-04-2018)

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Roza Szweda, Christophe Chendo, Laurence Charles, Paul N. W. Baxter, Jean-Francois Lutz. Synthesis of oligoarylacetylenes with defined conjugated sequences using tailor-made soluble polymer supports. Chemical Communications, 2017, 53 (59), pp.8312--8315. ⟨10.1039/c7cc03633g⟩. ⟨hal-01774186⟩
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