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Alkyne-induced carbyne-carbyne coupling in the trinuclear bis(carbyne) iron cluster Fe3(CO)9(.mu.3-COC2H5)(.mu.3-CCH3). X-ray structures of Fe3(CO)6(.mu.-CO)2.mu.3-.eta.4[C(OC2H5)C(CH3)C(C6H5)C(C6H5)] and Fe3(CO)6(.mu.-CO)2.mu.3-.eta.4[C(CH3)C(OC2H5)C(Si(CH3)3)C(Si(CH3)3)]

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https://hal.archives-ouvertes.fr/hal-01838171
Contributor : Didier Nuel Connect in order to contact the contributor
Submitted on : Friday, July 13, 2018 - 10:37:31 AM
Last modification on : Monday, July 4, 2022 - 8:59:09 AM

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Didier Nuel, Francoise Dahan, René Mathieu. Alkyne-induced carbyne-carbyne coupling in the trinuclear bis(carbyne) iron cluster Fe3(CO)9(.mu.3-COC2H5)(.mu.3-CCH3). X-ray structures of Fe3(CO)6(.mu.-CO)2.mu.3-.eta.4[C(OC2H5)C(CH3)C(C6H5)C(C6H5)] and Fe3(CO)6(.mu.-CO)2.mu.3-.eta.4[C(CH3)C(OC2H5)C(Si(CH3)3)C(Si(CH3)3)]. Journal of the American Chemical Society, American Chemical Society, 1985, 107 (6), pp.1658 - 1664. ⟨10.1021/ja00292a032⟩. ⟨hal-01838171⟩

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